Biosynthesis of ketomycin.

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Biosynthesis of ketomycin.

The antibiotic ketomycin is formed from shikimic acid via chorismic acid and prephenic acid. Phenylalanine and 2',5'-dihydrophenylalanine are not intermediates in the biosynthesis. Degradation of ketomycin derived from [1,6-14C]shikimic acid showed that prephenic acid is converted into ketomycin with stereospecific discrimination between the two enantiotopic edges of the ring, the pro-S-R edge ...

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ژورنال

عنوان ژورنال: The Journal of Antibiotics

سال: 1984

ISSN: 0021-8820,1881-1469

DOI: 10.7164/antibiotics.37.868